Ligand denticity controls enantiomeric preference in DNA-based asymmetric catalysis.
نویسندگان
چکیده
DNA-based catalysis can be used to control the enantioselectivity of copper-catalysed Diels-Alder and Friedel-Crafts reactions to produce either enantiomer of the product by changing the denticity of the ligand coordinated to the Cu(II) ion, even though the DNA adopts a right handed helical conformation only.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 18 شماره
صفحات -
تاریخ انتشار 2012